Browsing by Author "Kumarage, Gayan W. C."

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Enhancement of Photo-Electrical Properties of CdS Thin Films: Effect of N2 Purging and N2 Annealing
(2024) Sankalpa, Gayan K. L.; Kumarasinghe, Gayan R. K. K. G. R.; Dassanayake, Buddhika S.; Kumarage, Gayan W. C.
The impact of N2 purging in the CdS deposition bath and subsequent N2 annealing is examined and contrasted with conventional CdS films, which were deposited without purging and annealed in ambient air. All films were fabricated using the chemical bath deposition method at a temperature of 80 ◦C on fluorine-doped tin oxide glass slides (FTO). N2 purged films were deposited by introducing nitrogen gas into the deposition bath throughout the CdS deposition process. Subsequently, both N2 purged and un-purged films underwent annealing at temperatures ranging from 100 to 500 ◦C for one hour, either in a nitrogen or ambient air environment. Photoelectrochemical (PEC) cell studies reveal that films subjected to both N2 purging and N2 annealing exhibit a notable enhancement of 37.5% and 27% in ISC (short-circuit current) and VOC (open-circuit voltage) values, accompanied by a 5% improvement in optical transmittance compared to conventional CdS thin films. The films annealed at 300 ◦C demonstrate the highest ISC, VOC, and VFB values, 55 μA, 0.475 V, and−675 mV, respectively. The improved optoelectrical properties in both N2-purged and N2-annealed films are attributed to their well-packed structure, enhanced interconnectivity, and a higher sulfur to cadmium ratio of 0.76 in the films.
Nb2O5 Microcolumns for Ethanol Sensing
(2024) Kumarage, Gayan W. C.; Panamaldeniya, Shasika A.; Maraloiu, Valentin A.; Dassanayake, Buddhika S.; Gunawardhana, Nanda; Comini, Elisabetta
Pseudohexagonal Nb2O5 microcolumns spanning a size range of 50 to 610 nm were synthesized utilizing a cost-effective hydrothermal process (maintained at 180 ◦C for 30 min), followed by a subsequent calcination step at 500 ◦C for 3 h. Raman spectroscopy analysis unveiled three distinct reflection peaks at 220.04 cm−1, 602.01 cm−1, and 735.3 cm−1, indicative of the pseudohexagonal crystal lattice of Nb2O5. The HRTEM characterization confirmed the inter-lattice distance of 1.8 Å for the 110 plain and 3.17 Å for the 100 plain. The conductometry sensors were fabricated by drop-casting a dispersion of Nb2O5 microcolumns, in ethanol, on Pt electrodes. The fabricated sensors exhibited excellent selectivity in detecting C2H5OH (ΔG/G = 2.51 for 10 ppm C2H5OH) when compared to a variety of tested gases, including CO, CO2, NO2, H2, H2S, and C3H6O. The optimal operating temperature for this selective detection was determined to be 500 ◦C in a dry air environment. Moreover, the sensors demonstrated exceptional repeatability over the course of three testing cycles and displayed strong humidity resistance, even when exposed to 90% relative humidity. This excellent humidity resistance gas sensing property can be attributed to their nanoporous nature and elevated operating temperature.