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    Observation of n-type Photoconductivty in Electrodeposited Copper Oxide Film Electrodes in a Photoelectrochemical cell
    (Solar Energy Materials, 1986) Siripala, W.; Jayakody, J.R.P.
    Copper oxide films were cathodically deposited on various metal substrates (Cu, Ti and Pt) using a basic solution of CuSO4, and it is found that they produce n-type photoconductivity in a photoelectrochemical cell. The photoresponse of these films is more pronounced than the previously known thermally grown p-Cu2O films, and the n-type behaviour could be converted to p-type by heating the samples in air. It is tentatively proposed that oxygen ion vacancies in the electrodeposited copper oxide films would result in n-Cu2O.
  • Item
    A Photoelectrochemical Investigation of n- and p-type semi�conducting behaviour of Copper Oxide Films
    (Semiconductor Science and Technology, 1989) Siripala W; Kumara K P
    Copper(I) oxide films were prepared on copper substrates by exposing them to solutions containing Cu2+ ions, and it was observed that the photoresponse of these films electrodes in a photoelectrochemical cell is both n- and p-type. However, it was observed that the n-type behaviour of these film electrodes could be enhanced and the p-type behaviour could be reduced by adjusting the pH of the solution in which the oxide films had been prepared. The simultaneous existence of spatially separated n- and p-type regions in the Cu2O film is suggested as the possible reason for these observations. The anodic oxidation of copper was considered to be the origin of the p-type regions while the n-type regions were considered to be the result of the cathodic deposition of Cu2O.