Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation

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dc.contributor.authorHutchins, K.M.
dc.contributor.authorRupasinghe, T.P.
dc.contributor.authorDitzler, L.R.
dc.contributor.authorSwenson, D.C.
dc.contributor.authorSander, J.R.G.
dc.contributor.authorBaltrusaitis, J.
dc.contributor.authorTivanski, A.V.
dc.contributor.authorMacGillivray, L.R.
dc.date.accessioned2017-11-08T03:19:43Z
dc.date.available2017-11-08T03:19:43Z
dc.date.issued2014
dc.description.abstractAg(I) is used to form a π-stacked metal–organic solid that exhibits remarkably high electrical conductivity. The solid undergoes a single-crystal-to-single-crystal [2+2] photodimerization to generate a 1D coordination polymer with over 40% higher conductivity. The Ag(I) complex represents the first example of an increase in conductivity resulting from a [2+2] photodimerization. Density of states calculations show a higher contribution from Ag(I) ions to the valence band in the photodimerized solid, supporting the increase in conductivity.en_US
dc.identifier.citationHutchins, K.M., Rupasinghe, T.P., Ditzler, L.R., Swenson, D.C., Sander, J.R.G., Baltrusaitis, J., Tivanski, A.V., and MacGillivray, L.R., (2014). Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation, American Chemical Society. Vol 136 (19). 6778-6781.en_US
dc.identifier.urihttp://repository.kln.ac.lk/handle/123456789/17955
dc.language.isoenen_US
dc.publisherAmerican Chemical Society.en_US
dc.titleNanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformationen_US
dc.typeArticleen_US

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